catena-Poly[[triphenyltin(IV)]-μ-3-methylphenylseleninato-κ2 O:O′]
نویسندگان
چکیده
In the polymeric title coordination compound, [Sn(C(6)H(5))(3)(C(7)H(7)O(2)Se)](n), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms from two symmetry-related bridging seleninate ligands in axial positions and three phenyl groups in the equatorial plane. In the crystal, the complex exhibits a zigzag chain structure running parallel to the c axis. An intra-chain C-H⋯O hydrogen bond is observed.
منابع مشابه
catena-Poly[[triphenyltin(IV)]-μ-phenylphosphinato-κ2 O:O′]
In the structure of the title coordination polymer, [Sn(C(6)H(5))(3)(C(6)H(6)O(2)P)](n) or [PhP(H)O(2)Sn(IV)(Ph)(3)](n), the Sn(IV) atom is five-coordinate, with the SnC(3)O(2) framework in a trans trigonal-bipyramidal arrangement having the PhP(H)O(2) (-) anions in apical positions. In the crystal, neighbouring polymer chains are linked via C-H⋯π inter-actions, forming a two-dimensional networ...
متن کاملcatena-Poly[[triphenyltin(IV)]-μ-2-[(3,5-di-tert-butyl-4-hydroxybenzyl)sulfanyl]acetato-κ2 O:O′]
The title compound, [Sn(C(6)H(5))(3)(C(17)H(25)O(3)S)](n), comprises two symmetry-independent five-coordinated triphenyl-tin mol-ecules which are linked by carboxyl-ate bridges into a polymeric chain. The Sn(IV) atom is in a distorted trans-C(3)SnO(2) trigonal-bipyramidal geometry. The presence of two bulky tert-butyl groups on the benzene ring prevents any hydrogen-bonding inter-actions involv...
متن کاملcatena-Poly[[trimethyltin(IV)]-μ-5-methylthiophene-2-carboxylato-κ2 O:O′]
In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)S)](n), which contains two formula units in the asymmetric unit, the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of the ligands in axial positions and three methyl groups in equatorial positions. Adjacent Sn(IV) atoms are bridged by the ligands, thereby forming a chain propagating in [010].
متن کاملcatena-Poly[[trimethyltin(IV)]-μ-phenylseleninato-κ2 O:O′]
In the title polymeric coordination compound, [Sn(CH(3))(3)(C(6)H(5)O(2)Se)](n), the Sn(IV) atom has a distorted trigonal-bipyramidal geometry, with two O atoms of two symmetry-related bridging phenyl-seleninate anions in axial positions and three methyl groups in equatorial positions. In the crystal, the complex exhibits a chain structure parallel to the b axis.
متن کاملcatena-Poly[[trimethyltin(IV)]-μ-2,5-difluorobenzoato-κ2 O:O′]
In the title polymeric coordination compound, [Sn(CH(3))(3)(C(7)H(3)F(2)O(2))](n), the Sn atom exhibits a distorted trigonal-bipyramidal coordination geometry with the carboxyl-ate O atoms in the axial positions and the equatorial positions occupied by the methyl groups. The two Sn-O bond lengths are 2.225 (5) and 2.410 (6) Å.
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عنوان ژورنال:
دوره 67 شماره
صفحات -
تاریخ انتشار 2011